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Department of Applied Chemistry, Graduate School of Engineering, Osaka University


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Prof. Tsuyoshi Inoue, Dr. Eiichi Mizohata (Osaka University, Japan)

Collaborator:
Prof. Tsuyoshi Inoue (Osaka University, Japan)
Dr. Eiichi Mizohata 

Web site:
http://www.chem.eng.osaka-u.ac.jp/~inoue-tken/index.html

Publication:
1. “Crystal Structures and Coordination Behavior of Aqua- and Cyano-Co(III) Tetradehydrocorrins in the Heme Pocket of Myoglobin”
Yoshitsugu Morita, Koji Oohora, Eiichi Mizohata, Akiyoshi Sawada, Takashi Kamachi, Kazunari Yoshizawa, Tsuyoshi Inoue, and Takashi Hayashi*
Inorg. Chem., 55, 1287–1295 (2016) DOI: 10.1021/acs.inorgchem.5b02598.

2. “A Highly Active Biohybrid Catalyst for Olefin Metathesis in Water: Impact of a Hydrophobic Cavity in a β-Barrel Protein”
Daniel F. Sauer, Tomoki Himiyama, Kengo Tachikawa, Kazuki Fukumoto, Akira Onoda, Eiichi Mizohata, Tsuyoshi Inoue, Marco Bocola, Ulrich Schwaneberg, Takashi Hayashi,* and Jun Okuda*
ACS Catal., 5, 7519–7522 (2015).   DOI: 10.1021/acscatal.5b01792.

3. “Co(II)/Co(I) Reduction-induced Axial Histidine-flipping in Myoglobin Reconstituted with a Cobalt Tetradehydrocorrin as a Methionine Synthase Model”
Takashi Hayashi,* Yoshitsugu Morita, Eiichi Mizohata, Koji Oohora, Jun Ohbayashi, Tsuyoshi Inoue, and Yoshio Hisaeda
Chem. Commun., 50, 12560–12563 (2014). Open Access. DOI : 10.1039/C4CC05448B.

4. “A Rhodium Complex-linked Hybrid Biocatalyst: Stereo-controlled Phenylacetylene Polymerization within an Engineered Protein Cavity”
Kazuki Fukumoto, Akira Onoda,  Eiichi Mizohata, Marco Bocola, Tsuyoshi Inoue, Ulrich Schwaneberg, and Takashi Hayashi*
ChemCatChem, 6, 1229–1235 (2014). Front Cover. DOI: 10.1002/cctc.201301055.

5. “C(sp3)–H Bond Hydroxylation Catalyzed by Myoglobin Reconstituted with Manganese Porphycene”
Koji Oohora, Yushi Kihira, Eiichi Mizohata, Tsuyoshi Inoue, and Takashi Hayashi*
J. Am. Chem. Soc., 135, 17282–17285 (2013). DOI: 10.1021/ja409404k


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