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Department of Applied Chemistry, Graduate School of Engineering, Osaka University


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Prof. Yoshitsugu Shiro (University of Hyogo, Japan), Dr. Hiroshi Sugimoto (RIKEN)

Collaborator:
Prof. Yoshitsugu Shiro (University of Hyogo, Japan), Dr. Hiroshi Sugimoto (RIKEN)

Web site:
http://www.sci.u-hyogo.ac.jp/life/regulation/index-j.html
http://www.riken.jp/biometal/index.htm  

Publication:
1. “Manganese(V) Porphycene Complex Responsible for Inert C–H Bond Hydroxylation in a Myoglobin Matrix”
Koji Oohora,* Hiroyuki Meichin, Yushi Kihira, Hiroshi Sugimoto, Yoshitsugu Shiro, and Takashi Hayashi*
J. Am. Chem. Soc., 139, 18460–18463 (2017), DOI:10.1021/jacs.7b11288.

2. “H2O2-dependent Substrate Oxidation by an Engineered Diiron Site in a Bacterial Hemerythrin”
Yasunori Okamoto, Akira Onoda,* Hiroshi Sugimoto, Yu Takano, Shun Hirota, Donald M. Kurtz Jr., Yoshitsugu Shiro,  and Takashi Hayashi*
Chem. Commun., 50, 3421–3423 (2014). Front Cover. DOI : 10.1039/c3cc48108e.

3. “Crystal Structure, Exogenous Ligand Binding and Redox Properties of an Engineered Diiron Active Site in a Bacterial Hemerythrin”
Yasunori Okamoto, Akira Onoda,* Hiroshi Sugimoto, Yu Takano, Shun Hirota, Donald M. Kurtz Jr., Yoshitsugu Shiro, and Takashi Hayashi*
Inorg. Chem., 52, 13014–13020 (2013). DOI: 10.1021/ic401632x

4. “Crystal Structure and Spectroscopic Studies of a Stable Mixed-Valent State of the Hemerythrin-like Domain of a Bacterial Chemotaxis Protein”
Akira Onoda,* Yasunori Okamoto, Hiroshi Sugimoto, Yoshitsugu Shiro, and Takashi Hayashi*
Inorg. Chem., 50, 4892-4899, (2011). DOI:10.1021/ic2001267


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